| 1 |
REQUIRE "system.a4l"; |
| 2 |
REQUIRE "atoms.a4l"; |
| 3 |
REQUIRE "johnpye/thermo_types.a4c"; |
| 4 |
|
| 5 |
(************************************************************************* |
| 6 |
|
| 7 |
The thermodynamic properties of water calculated with the |
| 8 |
IAPWS95 equations. Variables and units: |
| 9 |
|
| 10 |
T Temperature, K |
| 11 |
rho Density, kg/m^3 |
| 12 |
p Pressure, MPa |
| 13 |
u Specific internal energy, kJ/kg |
| 14 |
h Specific enthalpy, kJ/kg |
| 15 |
s Specific entropy, kJ/(kg*K) |
| 16 |
cv Isochoric specific heat, kJ/(kg*K) |
| 17 |
cp Isobaric specific heat, kJ/(kg*K) |
| 18 |
w Speed of sound, m/s |
| 19 |
|
| 20 |
References: |
| 21 |
|
| 22 |
[1] The International Association for the Properties of |
| 23 |
Water and Steam, "Release on the IAPWS Formulation 1995 |
| 24 |
for the Thermodynamic Properties of Ordinary Water |
| 25 |
Substance for General and Scientific Use", dated |
| 26 |
September 1996, Fredericia, Denmark. See the "Releases" |
| 27 |
section of the website http://www.iapws.org/. |
| 28 |
|
| 29 |
[2] NIST Chemistry Webbook: |
| 30 |
http://webbook.nist.gov/chemistry/fluid/ |
| 31 |
|
| 32 |
---------------------------------------------------------------------- |
| 33 |
|
| 34 |
freesteam-ascend - IAPWS-95 steam library for ASCEND |
| 35 |
Copyright (C) John Pye 2005 |
| 36 |
derived from work by Don Peterson for freesteam, (C) 2004. |
| 37 |
|
| 38 |
This program is free software; you can redistribute it |
| 39 |
and/or modify it under the terms of the GNU General Public |
| 40 |
License as published by the Free Software Foundation; either |
| 41 |
version 2 of the License, or (at your option) any later |
| 42 |
version. |
| 43 |
|
| 44 |
This program is distributed in the hope that it will be |
| 45 |
useful, but WITHOUT ANY WARRANTY; without even the implied |
| 46 |
warranty of MERCHANTABILITY or FITNESS FOR A PARTICULAR |
| 47 |
PURPOSE. See the GNU General Public License for more |
| 48 |
details. |
| 49 |
|
| 50 |
You should have received a copy of the GNU General Public |
| 51 |
License along with this program; if not, write to the Free |
| 52 |
Software Foundation, Inc., 59 Temple Place, Suite 330, |
| 53 |
Boston, MA 02111-1307 USA |
| 54 |
|
| 55 |
*) |
| 56 |
|
| 57 |
MODEL steam_state; |
| 58 |
|
| 59 |
delta IS_A factor; |
| 60 |
tau IS_A factor; |
| 61 |
|
| 62 |
rho IS_A mass_density; |
| 63 |
T IS_A temperature; |
| 64 |
|
| 65 |
(*-------------- CONSTANTS ---------------*) |
| 66 |
rhoc IS_A mass_density_constant; |
| 67 |
Tc IS_A temperature_constant; |
| 68 |
|
| 69 |
rhoc "density of water at the critical point" |
| 70 |
:== 322 {kg/m^3}; |
| 71 |
|
| 72 |
Tc "temperature of water at the critical point" |
| 73 |
:== 647.096 {K}; |
| 74 |
|
| 75 |
tau = Tc / T; |
| 76 |
delta = rho / rhoc; |
| 77 |
|
| 78 |
|
| 79 |
range_0 IS_A set OF integer_constant; |
| 80 |
range_0 :== [1..8]; |
| 81 |
|
| 82 |
range_01 IS_A set OF integer_constant; |
| 83 |
range_01 :== [4..8]; |
| 84 |
|
| 85 |
range_r1 IS_A set OF integer_constant; |
| 86 |
range_r1 :== [1..7]; |
| 87 |
|
| 88 |
range_r2 IS_A set OF integer_constant; |
| 89 |
range_r2 :== [8..51]; |
| 90 |
|
| 91 |
range_r3 IS_A set OF integer_constant; |
| 92 |
range_r3 :== [52..54]; |
| 93 |
|
| 94 |
range_r4 IS_A set OF integer_constant; |
| 95 |
range_r4 :== [55..56]; |
| 96 |
|
| 97 |
n0[range_0] IS_A real_constant; |
| 98 |
n0[1] :== -8.32044648201; |
| 99 |
|
| 100 |
n0[2] :== 6.6832105268; |
| 101 |
n0[3] :== 3.00632; |
| 102 |
n0[4] :== 0.012436; |
| 103 |
|
| 104 |
n0[5] :== 0.97315; |
| 105 |
n0[6] :== 1.27950; |
| 106 |
n0[7] :== 0.96956; |
| 107 |
n0[8] :== 0.24873; |
| 108 |
|
| 109 |
gamma0[range_01] IS_A real_constant; |
| 110 |
gamma0[4] :== 1.28728967; |
| 111 |
gamma0[5] :== 3.53734222; |
| 112 |
gamma0[6] :== 7.74073708; |
| 113 |
gamma0[7] :== 9.24437796; |
| 114 |
gamma0[8] :== 27.5075105; |
| 115 |
|
| 116 |
n[1..56] IS_A real_constant; |
| 117 |
n[1] :== 0.12533547935523e-1; n[2] :== 0.78957634722828e+1; n[3] :== -0.87803203303561e+1; n[4] :== 0.31802509345418e+0; |
| 118 |
n[5] :== -0.26145533859358e+0; n[6] :== -0.78199751687981e-2; n[7] :== 0.88089493102134e-2; |
| 119 |
n[8] :== -0.66856572307965e+0; n[9] :== 0.20433810950965e+0; n[10] :== -0.66212605039687e-4; |
| 120 |
n[11] :== -0.19232721156002e+0; n[12] :== -0.25709043003438e+0; n[13] :== 0.16074868486251e+0; n[14] :== -0.40092828925807e-1; |
| 121 |
n[15] :== 0.39343422603254e-6; n[16] :== -0.75941377088144e-5; n[17] :== 0.56250979351888e-3; |
| 122 |
n[18] :== -0.15608652257135e-4; n[19] :== 0.11537996422951e-8; n[20] :== 0.36582165144204e-6; |
| 123 |
n[21] :== -0.13251180074668e-11; n[22] :== -0.62639586912454e-9; n[23] :== -0.10793600908932e+0; n[24] :== 0.17611491008752e-1; |
| 124 |
n[25] :== 0.22132295167546e+0; n[26] :== -0.40247669763528e+0; n[27] :== 0.58083399985759e+0; |
| 125 |
n[28] :== 0.49969146990806e-2; n[29] :== -0.31358700712549e-1; n[30] :== -0.74315929710341e+0; |
| 126 |
n[31] :== 0.47807329915480e+0; n[32] :== 0.20527940895948e-1; n[33] :== -0.13636435110343e+0; n[34] :== 0.14180634400617e-1; |
| 127 |
n[35] :== 0.83326504880713e-2; n[36] :== -0.29052336009585e-1; n[37] :== 0.38615085574206e-1; |
| 128 |
n[38] :== -0.20393486513704e-1; n[39] :== -0.16554050063734e-2; n[40] :== 0.19955571979541e-2; |
| 129 |
n[41] :== 0.15870308324157e-3; n[42] :== -0.16388568342530e-4; n[43] :== 0.43613615723811e-1; n[44] :== 0.34994005463765e-1; |
| 130 |
n[45] :== -0.76788197844621e-1; n[46] :== 0.22446277332006e-1; n[47] :== -0.62689710414685e-4; |
| 131 |
n[48] :== -0.55711118565645e-9; n[49] :== -0.19905718354408e+0; n[50] :== 0.31777497330738e+0; |
| 132 |
n[51] :== -0.11841182425981e+0; n[52] :== -0.31306260323435e+2; n[53] :== 0.31546140237781e+2; n[54] :== -0.25213154341695e+4; |
| 133 |
n[55] :== -0.14874640856724e+0; n[56] :== 0.31806110878444e+0; |
| 134 |
|
| 135 |
c[1..51] IS_A integer_constant; |
| 136 |
c[1] :== 0; c[2] :== 0; c[3] :== 0; c[4] :== 0; c[5] :== 0; |
| 137 |
c[6] :== 0; c[7] :== 0; c[8] :== 1; c[9] :== 1; c[10] :== 1; |
| 138 |
c[11] :== 1; c[12] :== 1; c[13] :== 1; c[14] :== 1; c[15] :== 1; |
| 139 |
c[16] :== 1; c[17] :== 1; c[18] :== 1; c[19] :== 1; c[20] :== 1; |
| 140 |
c[21] :== 1; c[22] :== 1; c[23] :== 2; c[24] :== 2; c[25] :== 2; |
| 141 |
c[26] :== 2; c[27] :== 2; c[28] :== 2; c[29] :== 2; c[30] :== 2; |
| 142 |
c[31] :== 2; c[32] :== 2; c[33] :== 2; c[34] :== 2; c[35] :== 2; |
| 143 |
c[36] :== 2; c[37] :== 2; c[38] :== 2; c[39] :== 2; c[40] :== 2; |
| 144 |
c[41] :== 2; c[42] :== 2; c[43] :== 3; c[44] :== 3; c[45] :== 3; |
| 145 |
c[46] :== 3; c[47] :== 4; c[48] :== 6; c[49] :== 6; c[50] :== 6; |
| 146 |
c[51] :== 6; |
| 147 |
|
| 148 |
d[1..54] IS_A integer_constant; |
| 149 |
d[1] :== 1; d[2] :== 1; d[3] :== 1; d[4] :== 2; d[5] :== 2; |
| 150 |
d[6] :== 3; d[7] :== 4; d[8] :== 1; d[9] :== 1; d[10] :== 1; |
| 151 |
d[11] :== 2; d[12] :== 2; d[13] :== 3; d[14] :== 4; d[15] :== 4; |
| 152 |
d[16] :== 5; d[17] :== 7; d[18] :== 9; d[19] :== 10; d[20] :== 11; |
| 153 |
d[21] :== 13; d[22] :== 15; d[23] :== 1; d[24] :== 2; d[25] :== 2; |
| 154 |
d[26] :== 2; d[27] :== 3; d[28] :== 4; d[29] :== 4; d[30] :== 4; |
| 155 |
d[31] :== 5; d[32] :== 6; d[33] :== 6; d[34] :== 7; d[35] :== 9; |
| 156 |
d[36] :== 9; d[37] :== 9; d[38] :== 9; d[39] :== 9; d[40] :== 10; |
| 157 |
d[41] :== 10; d[42] :== 12; d[43] :== 3; d[44] :== 4; d[45] :== 4; |
| 158 |
d[46] :== 5; d[47] :== 14; d[48] :== 3; d[49] :== 6; d[50] :== 6; |
| 159 |
d[51] :== 6; d[52] :== 3; d[53] :== 3; d[54] :== 3; |
| 160 |
|
| 161 |
t[1..54] IS_A real_constant; |
| 162 |
t[1] :== -0.5; t[2] :== 0.875; t[3] :== 1; t[4] :== 0.5; t[5] :== 0.75; |
| 163 |
t[6] :== 0.375; t[7] :== 1; t[8] :== 4; t[9] :== 6; t[10] :== 12; |
| 164 |
t[11] :== 1; t[12] :== 5; t[13] :== 4; t[14] :== 2; t[15] :== 13; |
| 165 |
t[16] :== 9; t[17] :== 3; t[18] :== 4; t[19] :== 11; t[20] :== 4; |
| 166 |
t[21] :== 13; t[22] :== 1; t[23] :== 7; t[24] :== 1; t[25] :== 9; |
| 167 |
t[26] :== 10; t[27] :== 10; t[28] :== 3; t[29] :== 7; t[30] :== 10; |
| 168 |
t[31] :== 10; t[32] :== 6; t[33] :== 10; t[34] :== 10; t[35] :== 1; |
| 169 |
t[36] :== 2; t[37] :== 3; t[38] :== 4; t[39] :== 8; t[40] :== 6; |
| 170 |
t[41] :== 9; t[42] :== 8; t[43] :== 16; t[44] :== 22; t[45] :== 23; |
| 171 |
t[46] :== 23; t[47] :== 10; t[48] :== 50; t[49] :== 44; t[50] :== 46; |
| 172 |
t[51] :== 50; t[52] :== 0; t[53] :== 1; t[54] :== 4; |
| 173 |
|
| 174 |
(* Correlation parameters *) |
| 175 |
|
| 176 |
(* TODO convert from C to ASCEND arrays? Note trickiness with 0- and 1-based array indices. *) |
| 177 |
|
| 178 |
a[range_r4] IS_A real_constant; |
| 179 |
a[55]:==3.5; |
| 180 |
a[56]:==3.5; |
| 181 |
|
| 182 |
b[range_r4] IS_A real_constant; |
| 183 |
b[55]:== 0.85; |
| 184 |
b[56]:== 0.95; |
| 185 |
|
| 186 |
A[range_r4] IS_A real_constant; |
| 187 |
A[55]:==0.32; |
| 188 |
A[56]:==0.32; |
| 189 |
|
| 190 |
B[range_r4] IS_A real_constant; |
| 191 |
B[55]:==0.2; |
| 192 |
B[56]:==0.2; |
| 193 |
|
| 194 |
C[range_r4] IS_A real_constant; |
| 195 |
C[55]:==28; |
| 196 |
C[56]:==32; |
| 197 |
|
| 198 |
D[range_r4] IS_A real_constant; |
| 199 |
D[55]:==700; |
| 200 |
D[56]:==800; |
| 201 |
|
| 202 |
beta_r4[range_r4] IS_A real_constant; |
| 203 |
beta_r4[55]:==0.3; |
| 204 |
beta_r4[56]:==0.3; |
| 205 |
|
| 206 |
alpha[range_r3] IS_A integer_constant; |
| 207 |
alpha[52]:==20; |
| 208 |
alpha[53]:==20; |
| 209 |
alpha[54]:==20; |
| 210 |
|
| 211 |
beta[range_r3] IS_A real_constant; |
| 212 |
beta[52]:==150; |
| 213 |
beta[53]:==150; |
| 214 |
beta[54]:==250; |
| 215 |
|
| 216 |
gamma[range_r3] IS_A real_constant; |
| 217 |
gamma[52]:==1.21; |
| 218 |
gamma[53]:==1.21; |
| 219 |
gamma[54]:==1.25; |
| 220 |
|
| 221 |
(*--------------- DIMENSIONLESS PARTIAL DERIVATIVES ---------------- *) |
| 222 |
|
| 223 |
(*------------ IDEAL PARTS ------------*) |
| 224 |
|
| 225 |
phi0 IS_A factor; |
| 226 |
phi0 = |
| 227 |
SUM[ n0[i]*ln(1-exp(-tau*gamma0[i])) | i IN [range_01] ] |
| 228 |
+ ln(delta) + n0[1] + n0[2]*tau + n0[3]*ln(tau); |
| 229 |
|
| 230 |
phi0delta IS_A factor; |
| 231 |
phi0delta = 1.0/delta; |
| 232 |
|
| 233 |
phi0deltadelta IS_A factor; |
| 234 |
phi0deltadelta = |
| 235 |
-1.0/(delta*delta); |
| 236 |
|
| 237 |
|
| 238 |
phi0tau IS_A factor; |
| 239 |
phi0tau = |
| 240 |
n0[2] + n0[3]/tau |
| 241 |
+ SUM[ n0[i]*gamma0[i]*(1/(1-exp(-tau*gamma0[i])) - 1) | i IN [range_01] ]; |
| 242 |
|
| 243 |
phi0deltatau IS_A real_constant; |
| 244 |
phi0deltatau :== 0.0; |
| 245 |
|
| 246 |
phi0tautau IS_A factor; |
| 247 |
phi0tautau |
| 248 |
= -n0[3]/(tau*tau) |
| 249 |
- SUM [ n0[i] * gamma0[i]^2 * exp(-tau*gamma0[i]) / ( 1 - exp(-tau*gamma0[i]) )^2 | i IN range_01 ]; |
| 250 |
|
| 251 |
(*----------- 'REAL' PARTS -- CLOSE YOUR EYES -----------*) |
| 252 |
|
| 253 |
d1 IS_A factor; |
| 254 |
d1 = delta - 1; |
| 255 |
|
| 256 |
t1 IS_A factor; |
| 257 |
t1 = tau -1; |
| 258 |
|
| 259 |
r3_b1[range_r3] IS_A factor; |
| 260 |
FOR i IN range_r3 CREATE |
| 261 |
r3_b1[i] = -alpha[i]*d1^2 - beta[i]* (tau - gamma[i])^2; |
| 262 |
END FOR; |
| 263 |
|
| 264 |
PSI[range_r4] IS_A factor; |
| 265 |
theta[range_r4] IS_A factor; |
| 266 |
DELTA[range_r4] IS_A factor; |
| 267 |
dDELTA_ddelta[range_r4] IS_A factor; |
| 268 |
dPSI_ddelta[range_r4] IS_A factor; |
| 269 |
dDELTAbi_ddelta[range_r4] IS_A factor; |
| 270 |
dDELTAbi_dtau[range_r4] IS_A factor; |
| 271 |
dPSI_dtau[range_r4] IS_A factor; |
| 272 |
d2DELTA_ddelta2[range_r4] IS_A factor; |
| 273 |
d2DELTAbi_ddelta2[range_r4] IS_A factor; |
| 274 |
d2PSI_ddelta2[range_r4] IS_A factor; |
| 275 |
d2DELTAbi_dtau2[range_r4] IS_A factor; |
| 276 |
d2PSI_dtau2[range_r4] IS_A factor; |
| 277 |
d2PSI_ddeltadtau[range_r4] IS_A factor; |
| 278 |
d2DELTAbi_ddeltadtau[range_r4] IS_A factor; |
| 279 |
|
| 280 |
FOR i IN range_r4 CREATE |
| 281 |
PSI[i] = exp(-C[i]*d1^2 - D[i]*t1^2); |
| 282 |
theta[i] = 1 - tau + A[i] * (d1^2)^( 1/(2 * beta_r4[i]) ); |
| 283 |
DELTA[i] = theta[i]^2 + B[i] * (d1^2)^a[i]; |
| 284 |
|
| 285 |
dDELTA_ddelta[i] = d1*(A[i]*theta[i]*2/beta_r4[i]* |
| 286 |
(d1^2)^(1/(2*beta_r4[i]) - 1) + 2*B[i]*a[i]* |
| 287 |
(d1^2)^(a[i] - 1) ); |
| 288 |
|
| 289 |
dPSI_ddelta[i] = -2*C[i]*d1*PSI[i]; |
| 290 |
|
| 291 |
dDELTAbi_ddelta[i] = b[i] * DELTA[i]^(b[i]-1) * dDELTA_ddelta[i]; |
| 292 |
|
| 293 |
dDELTAbi_dtau[i] = -2 * theta[i] * b[i] * DELTA[i]^(b[i]-1); |
| 294 |
dPSI_dtau[i] = -2 * D[i] * t1 * PSI[i]; |
| 295 |
|
| 296 |
d2PSI_ddelta2[i] = (2 * C[i] * d1^2 - 1) * 2 * C[i] * PSI[i]; |
| 297 |
|
| 298 |
d2DELTA_ddelta2[i] = 1/d1*dDELTA_ddelta[i] + d1^2*(4*B[i]*a[i]* |
| 299 |
(a[i]-1)*(d1^2)^(a[i]-2) + 2*A[i]^2* |
| 300 |
(1/(beta_r4[i]^2))*((d1^2) ^ (1/(2*beta_r4[i])-1))^2) + |
| 301 |
A[i]*theta[i]*4/beta_r4[i]*(1/(2*beta_r4[i]) - 1)* |
| 302 |
(d1^2)^(1/(2*beta_r4[i]) - 2); |
| 303 |
|
| 304 |
d2DELTAbi_ddelta2[i] =b[i]*(DELTA[i]^(b[i]-1) * |
| 305 |
d2DELTA_ddelta2[i] + (b[i]-1)*DELTA[i]^(b[i]-2)* |
| 306 |
dDELTA_ddelta[i]^2); |
| 307 |
|
| 308 |
d2DELTAbi_dtau2[i] = 2*b[i] * DELTA[i]^(b[i]-1) + |
| 309 |
4*theta[i]^2 * b[i]*(b[i]-1) * DELTA[i]^(b[i]-2); |
| 310 |
|
| 311 |
d2PSI_dtau2[i] = (2 * D[i] * t1^2 - 1) * 2 * D[i] * PSI[i]; |
| 312 |
|
| 313 |
d2PSI_ddeltadtau[i] = 4 * C[i] * D[i] * d1 * t1 * PSI[i]; |
| 314 |
|
| 315 |
d2DELTAbi_ddeltadtau[i] = -A[i] * b[i]*2/beta_r4[i] * |
| 316 |
DELTA[i]^(b[i]-1) * d1 * (d1^2)^(1/(2*beta_r4[i])-1) - |
| 317 |
2 * theta[i] * b[i] *(b[i]-1) * DELTA[i]^(b[i]-2) * |
| 318 |
dDELTA_ddelta[i]; |
| 319 |
|
| 320 |
END FOR; |
| 321 |
|
| 322 |
phir IS_A factor; |
| 323 |
phir "phir expr" |
| 324 |
= |
| 325 |
SUM[ n[i] * delta^d[i] * tau^t[i] | i IN [range_r1] ] |
| 326 |
+ |
| 327 |
SUM[ n[i] * delta^d[i] * tau^t[i] * |
| 328 |
exp(-delta^c[i]) | i IN [range_r2] ] |
| 329 |
+ |
| 330 |
SUM[ n[i] * delta^d[i] * tau^t[i] * exp( |
| 331 |
-alpha[i]*d1^2 - beta[i]* |
| 332 |
(tau - gamma[i])*(tau - gamma[i]) |
| 333 |
) | i IN [range_r3] ] |
| 334 |
+ |
| 335 |
SUM[ n[i] * DELTA[i]^b[i] * delta * PSI[i] | i IN [range_r4] ]; |
| 336 |
|
| 337 |
|
| 338 |
phirdelta IS_A factor; |
| 339 |
phirdelta = |
| 340 |
SUM[ n[i] * d[i] * delta^(d[i] - 1) * tau^t[i] | i IN range_r1 ] |
| 341 |
+ SUM[ n[i] * exp(-delta^c[i]) * (delta^(d[i]-1) * |
| 342 |
tau^t[i] * (d[i] - c[i] * delta^c[i]) ) | i IN range_r2 ] |
| 343 |
+ SUM[ n[i]*delta^d[i] * tau^t[i] * exp( r3_b1[i] ) * |
| 344 |
(d[i]/delta - 2*alpha[i]*d1) | i IN range_r3 ] |
| 345 |
+ SUM[ n[i] * ( |
| 346 |
DELTA[i]^b[i] * (PSI[i] + delta * dPSI_ddelta[i] ) |
| 347 |
+ dDELTAbi_ddelta[i] * delta * PSI[i] ) | i IN range_r4 ]; |
| 348 |
|
| 349 |
phirtau IS_A factor; |
| 350 |
phirtau = |
| 351 |
SUM[ n[i] * t[i] * delta^d[i] * tau^(t[i]-1) | i IN range_r1 ] |
| 352 |
+ SUM[ n[i]*t[i]*delta^d[i]*tau^(t[i]-1) * exp(-delta^c[i]) | i IN range_r2 ] |
| 353 |
+ SUM[ n[i] * delta^d[i] * tau^t[i] * exp( r3_b1[i] )* |
| 354 |
(t[i]/tau - 2*beta[i]*(tau - gamma[i])) | i IN range_r3 ] |
| 355 |
+ SUM[ n[i]*delta*(dDELTAbi_dtau[i] * PSI[i] + |
| 356 |
DELTA[i]^b[i]*dPSI_dtau[i]) | i IN range_r4 ]; |
| 357 |
|
| 358 |
|
| 359 |
phirdeltadelta IS_A factor; |
| 360 |
phirdeltadelta = |
| 361 |
SUM[ n[i] * d[i] * (d[i] - 1) * delta^(d[i]-2) * tau^t[i] | i IN range_r1 ] |
| 362 |
+ SUM[ n[i]*exp(-(delta^c[i]))*((delta^(d[i]-2))* |
| 363 |
(tau^t[i])*((d[i] - c[i]*(delta^c[i]))* |
| 364 |
(d[i]-1-c[i]*(delta^c[i])) - |
| 365 |
c[i]*c[i]*(delta^c[i]))) | i IN range_r2 ] |
| 366 |
+ SUM[ n[i]*(tau^t[i])*exp( r3_b1[i] )* |
| 367 |
(-2*alpha[i]*(delta^d[i]) + |
| 368 |
4*alpha[i]*alpha[i]*(delta^d[i])*d1^2 - |
| 369 |
4*d[i]*alpha[i]*(delta^(d[i]-1))*d1 + |
| 370 |
d[i]*(d[i]-1)*(delta^(d[i]-1))) | i IN range_r3 ] |
| 371 |
+ SUM[ n[i]*( |
| 372 |
DELTA[i]^b[i] * (2*dPSI_ddelta[i] + delta*d2PSI_ddelta2[i] ) |
| 373 |
+ 2*dDELTAbi_ddelta[i] * (PSI[i] + delta*dPSI_ddelta[i]) |
| 374 |
+ d2DELTAbi_ddelta2[i] * delta * PSI[i] ) | i IN range_r4 ]; |
| 375 |
|
| 376 |
phirtautau IS_A factor; |
| 377 |
phirtautau = |
| 378 |
SUM[ n[i] * t[i] * (t[i]-1) * delta^d[i] * |
| 379 |
tau^(t[i]-2) | i IN range_r1 ] |
| 380 |
+ SUM[ n[i]*t[i]*(t[i]-1)* delta^d[i] * |
| 381 |
tau^(t[i]-2) * exp(- delta^c[i] ) | i IN range_r2 ] |
| 382 |
+ SUM[ n[i] * delta^d[i] * tau^t[i] * exp( r3_b1[i] ) * |
| 383 |
( (t[i]/tau - 2*beta[i]* (tau - gamma[i]) )^2 - |
| 384 |
t[i]/tau^2 - 2*beta[i] ) | i IN range_r3 ] |
| 385 |
+ SUM[ n[i] * delta * (d2DELTAbi_dtau2[i] * PSI[i] + |
| 386 |
2 * dDELTAbi_dtau[i] * dPSI_dtau[i] + DELTA[i]^b[i] * d2PSI_dtau2[i] ) | i IN range_r4 ]; |
| 387 |
|
| 388 |
phirdeltatau IS_A factor; |
| 389 |
phirdeltatau = |
| 390 |
SUM[ n[i]*d[i]*t[i] * delta^(d[i]-1) * tau^(t[i]-1) | i IN range_r1 ] |
| 391 |
|
| 392 |
+ SUM[ n[i]*t[i] * delta^(d[i]-1) * tau^(t[i]-1) |
| 393 |
* (d[i] - c[i] * delta^c[i] * exp(-delta^c[i]) ) | i IN range_r2 ] |
| 394 |
+ SUM[ n[i] * delta^d[i] * tau^t[i] * exp( r3_b1[i] ) * |
| 395 |
(d[i]/delta - 2*alpha[i]*d1) * (t[i]/tau - 2*beta[i]* (tau - gamma[i]) ) | i IN range_r3 ] |
| 396 |
+ SUM[ n[i]*( DELTA[i]^b[i] * (dPSI_dtau[i] + delta * |
| 397 |
d2PSI_ddeltadtau[i] ) + delta * dDELTAbi_ddelta[i] * dPSI_dtau[i] + |
| 398 |
dDELTAbi_dtau[i] * (PSI[i] + delta * dPSI_ddelta[i] ) + |
| 399 |
d2DELTAbi_ddeltadtau[i] * delta * PSI[i] ) | i IN range_r4 ]; |
| 400 |
|
| 401 |
(*--------- THERMO PROPERTY RELATIONS ----------- *) |
| 402 |
|
| 403 |
p IS_A pressure; |
| 404 |
u IS_A specific_energy; |
| 405 |
h IS_A specific_enthalpy; |
| 406 |
s IS_A specific_entropy; |
| 407 |
cp IS_A specific_heat_capacity; |
| 408 |
cv IS_A specific_heat_capacity; |
| 409 |
w IS_A speed; |
| 410 |
|
| 411 |
pressure: p |
| 412 |
= rho*(1{GAS_C})*T*(1 + delta*phirdelta); |
| 413 |
|
| 414 |
internal_energy: u |
| 415 |
= (1{GAS_C})*T*tau*(phi0tau + phirtau); |
| 416 |
|
| 417 |
enthalpy: h |
| 418 |
= (1{GAS_C})*T*(1 + tau*(phi0tau + phirtau) + delta*phirdelta); |
| 419 |
|
| 420 |
entropy: s |
| 421 |
= (1{GAS_C})*(tau*(phi0tau + phirtau) - phi0 - phir); |
| 422 |
|
| 423 |
c_isochoric: cv |
| 424 |
= -(1{GAS_C})*tau*tau*(phi0tautau + phirtautau); |
| 425 |
|
| 426 |
c_isobaric: cp |
| 427 |
= (1{GAS_C})*( -tau*tau*(phi0tautau + phirtautau) + |
| 428 |
( 1 + delta*phirdelta - delta*tau*phirdeltatau )^2 |
| 429 |
/ ( 1 + 2*delta*phirdelta + delta*delta*phirdeltadelta) |
| 430 |
); |
| 431 |
|
| 432 |
spd_sound: w |
| 433 |
= sqrt((1{GAS_C})*T* ( 1 + 2*delta*phirdelta + delta*delta*phirdeltadelta - |
| 434 |
( 1 + delta*phirdelta - delta*tau*phirdeltatau )^2 |
| 435 |
/ ( tau*tau*(phi0tautau + phirtautau) ) |
| 436 |
)); |
| 437 |
|
| 438 |
|
| 439 |
METHODS |
| 440 |
METHOD default_self; |
| 441 |
(* nothing here *) |
| 442 |
END default_self; |
| 443 |
|
| 444 |
METHOD specify; |
| 445 |
FIX T; |
| 446 |
FIX rho; |
| 447 |
END specify; |
| 448 |
|
| 449 |
METHOD values; |
| 450 |
T := 290 {K}; |
| 451 |
rho := 997 {kg/m^3}; |
| 452 |
END values; |
| 453 |
|
| 454 |
END steam_state; |
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